Ruby Gold Jewellery Diamond Necklace.
By Mans Women Jewellery
Crystal structure of ruby showing the substitution of Al3+ ions (blue) with Cr3+ (red). The substitution density of Cr3+ ions in this model is approximately 2%, approximating the maximum doping normally encountered.
When a chromium atom replaces an occasional aluminum atom, it too loses 3 electrons to become a chromium3+ ion to maintain the charge balance of the Al2O3 crystal. However, the Cr3+ ions are larger and have electron orbitals in different directions than aluminum. The octahedral arrangement of the O2− ions is distorted, and the energy levels of the different orbitals of those Cr3+ ions are slightly altered because of the directions to the O2− ions. Those energy differences correspond to absorption in the ultraviolet, violet, and yellow-green regions of the spectrum.
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